Chemistry with a Twist
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sandra bolaño gracía

recent publications:

  • "The catalytic role of extra molecules in the aminolysis or the heterolytic cleavage of an iridium alkoxycarbene complex" Talavera, M.; Bolaño, S.; Bravo, J.; García-Fontán, S., J. M. Hermida-Ramón. Eur. J. Inorg. Chem. 4024-4031, 2015.
  • “Electronic effects of substituents on the stability of the iridanaphthalene compound [IrCp*{=C(OMe)CH=C(o-C6H4)(Ph)}(PMe3)]PF6” M. Talavera, J. Bravo, J. Castro, S. García-Fontán, J. M. Hermida-Ramón, S. Bolaño. Dalton Transactions, 43, 17366-17374, 2014.
  • “[IrCp*(NCMe)2(PPh2Me)][PF6]2 as Catalyst for the Meyer–Schuster Rearrangement of Arylpropargylic Alcohols under Mild Conditions” M. Talavera, J. Bravo, L. Gonsalvi, M. Peruzzini, C. Zuccaccia, S. Bolaño. Eur. J. Inorg. Chem. 6268-6274, 2014.      
  • “Cyclometalated Iridium Complexes from Intramolecular C–H Activation of [IrCp*Cl{=C(OMe)CH=C(CH3)R}L] (R = CH3, Ph; L = PPh2Me, PMe3)” Talavera, M.; Bolaño, S.; Bravo, J.; Castro, J.; García-Fontán, S. Organometallics, 32, 7241-7244, 2013.
  • “Nucleophilic Attack in Methoxycarbenes: Heterolytic Cleavage of the Carbon (sp3)-Oxygen Bond versus Aminolysis” Talavera, M.; Bolaño, S.; Bravo, J.; Castro, J.; García-Fontán, S.; Hermida-Ramón, J. M. Organometallics, 32, 4402-4408, 2013.
  • “ Formation of Indanone from an Iridanaphthalene Complex” Talavera, M.; Bolaño, S.; Bravo, J.; Castro, J.; García-Fontán, S.; Hermida-Ramón, J. M. Organometallics, 32, 4058- 4060, 2013.
  • “Iridium-EDTA as an Efficient and Readily Available Catalyst for Water Oxidation” Arianna Savini, Gianfranco Bellachioma, Sandra Bolaño, Luca Rocchigiani, Cristiano Zuccaccia, Daniele Zuccaccia, Alceo Macchioni. Chem.Sus.Chem., 5, 1415-1419, 2012.
  • “Synthesis and characterization of new pentamethylcyclopentadienyl iridium hydride complexes” María Talavera, Sandra Bolaño, Jorge Bravo, Jesús Castro, Soledad García-Fontán.  J. Organomet. Chem.,715, 113-118, 2012.
  • “An NMR Study of the Oxidative Degradation of Cp*Ir Catalysts for Water Oxidation: Evidence for a Preliminary Attack on the Quaternary Carbon Atom of the –C–CH3 Moiety” Cristiano Zuccaccia, Gianfranco Bellachioma, Sandra Bolaño, Luca Rocchigiani,Arianna Savini, Alceo Macchioni. Eur. J. Inorg. Chem.,1462-1468, 2012.
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  • Chemistry with a Twist
  • People
  • Research
    • Chiroptical Systems >
      • Helical Molecular Orbitals
      • Chiroptical Systems due to Chiral Axes
      • Chiroptical Symmetry Analysis
      • Chiroptical Surfaces & More
    • Metallaaromatic Systems >
      • Metallacycles & More
      • Metallaaromatic Systems
      • Metallaaromatic Biaryl Atropisomers
      • Metallaaromatic Spirobifluorenes
    • Simulations
    • Lab on a Chip
  • Publications
    • Articles
    • Conferences
    • Outreach
  • Funding
  • Contact
    • Links
    • Settings