Chemistry with a Twist
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    • Chiroptical Systems >
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Articles

Design & Synthesis of Robust Chiroptical Systems
J. L. Alonso-Gómez, in preparation for invitation

Optical and Electrochemical Properties of Spirobifluorene Iridanaphthalene Complexes
M. Talavera, R. Pereira-Cameselle, Á. Peña-Gallego, I. Vázquez-Carballo, I. Prieto, J. L. Alonso-Gómez, S. Bolaño
Dalton Transactions, 2022, accepted

A Tetracyanobutadiene Spirobifluorene: Synthesis, Enantiomeric Resolution and Chiroptical Properties 
A. Ozcelik, Á. Peña-Gallego, R. Pereira-Cameselle, J. L. Alonso-Gómez
European Journal of Organic Chemistry, 2022, 
87, e202101333

ON/OFF Spiroconjugation via Peripheral Functionalization: Impact on the Reactivity and Chiroptical Properties of Spirobifluorenes 
Ani Ozcelik, Daniel Aranda, Raquel Pereira-Cameselle, María Talavera, Berta Covelo, Fabrizio Santoro, Ángeles Peña-Gallego, J. Lorenzo Alonso-Gómez
ChemPlusChem, 2022, 87, 202100554

Accessible Triplet Excited States in the Photoisomerization of Allenes with Extended Conjugation
J. Álvarez-García, R. García-Lago, J. L. Alonso-Gómez, C. Silva López, M. M. Cid
Dalton Trans., 2022, 51, 1357-1363
​
Chemoselectivity on the synthesis of iridacycles: a theoretical and experimental study
R. Pereira-Cameselle, A. Peña-Gallego, K. M. Cid-Seara, J. L. Alonso-Gómez, M. Talavera, S. Bolaño
Inorganica Chimica Acta, 2021, 517, 120189

Distinct helical molecular orbitals through conformational lock
A. Ozcelik, D. Aranda, S. Gil-Guerrero, X. A. Pola-Otero, M. Talavera, L. Wang, S. Kumar Behera,  J. Gierschner, Á. Peña-Gallego, F. Santoro, R. Pereira-Cameselle, J. L. Alonso-Gómez
Chem. Eur. J. 2020, 26, 17342–17349

From Allenes to Spiranes: on the Way to Device-compatible Chiroptical Systems
A. Ozcelik, Á. Peña-Gallego, R. Pereira-Cameselle, J. L. Alonso-Gómez
Current Organic Chemistry, 2020, 24, 23

Innovative Sensors for Age-related Diseases
M.F. Frasco, F.T.C. Moreira, G. Martins, Y. Castaño‐Guerrero, M.C.C.G. Carneiro, L. da Rocha, R. Pereira‐Cameselle, A. Ozcelik, S. Bolaño, J.L. Alonso‐Gómez, A. Riveiro, S. Chiussi, A.L. Oliveira, A. Sousa‐Castillo, M.A. Correa‐Duarte, M.G.F. Sales
book chapter, 2020, ISBN: 978-84-8158-832-3

Chiroptical Sensing​: a Conceptual Introduction
A. Ozcelik, R. Pereira-Cameselle, Natasa Poklar, A. G. Petrovic,  J. L. Alonso-Gómez
Sensors, 2020, 20, 974

Design and Synthesis of Chiral Spirobifluorenes
A. Ozcelik, Á. Peña-Gallego, R. Pereira-Cameselle, J. L. Alonso-Gómez
Chirality, 2020, 10.1002/chir.23186

Aromatic Interactions of Allenyl-anthracene Derivatives with pi-electron Acceptor Molecules:
an Experimental and Computational Study​

A. Vidal-Vidal, J. L. Alonso-Gómez, M. M. Cid, M. Marin-Luna
​Supramolecular Chemistry, 2020, 32(1), 39-48

Chiroptical Symmetry Analysis of Trianglimines: A Case Study
 A. Ozcelik, R. Pereira-Cameselle, R. A. Mosquera, Á. Peña-Gallego, J. L. Alonso-Gómez
Symmetry, 2019, 11, 1245

Spirobifluorene Metallaaromatics
 V. Arias-Coronado, R. Pereira-Cameselle, M. Talavera, A. Ozcelik, A. Peña-Gallego, J. L. Alonso-Gómez,  S. Bolaño
Chemistry - A European Journal​, 2019, 25, 13496-13499

Chiroptical Symmetry Analysis: Exciton Chirality-Based Formulae to Understand the Chiroptical Responses of Cn and Dn Symmetric Systems
S. Castro-Fernández, A. Peña-Gallego, R. A. Mosquera, J. L. Alonso-Gómez
Molecules, 2019, 24, 141

Metallaaromatic Biaryl Atropisomers
M. Talavera, A. Peña-Gallego, J. L. Alonso-Gómez, S. Bolaño
Chem. Commun., 2018, 54, 10974–10976

Rhodafuran from a Methoxy(alkenyl)carbene by the Rhoda-1,3,5-hexatriene Route
M. Talavera,  R. Pereira,  S. Bolaño
Dalton Transition, 2018, 47, 9064–9071

Device-compatible Chiroptical Surfaces through Self-assembly of Enantiopure Allenes
A. Ozcelik, R. Pereira-Cameselle, A. von Weber, M. Paszkiewicz, M. Carlotti, T. Paintner, L. Zhang, T. Lin, Y.-Q. Zhang, J.V. Barth, T. Nobelen, R. C. Chiechi, M. Jakob, U. Heiz, S. Chiussi, A. Kartouzian, F. Klappenberger, J.L. Alonso-Gómez
Langmuir, 2018, 34 (15),  4548–4553

Diverse Chiral Scaffolds from Diethynylspiranes: All-Carbon Double Helices and Flexible Shape-Persistent Macrocycles
S. Castro-Fernández, R. Yang, A. P. García, I. L. Garzón, H. Xu, A. G. Petrovic, J. L. Alonso-Gómez,
Chemistry - A European Journal, 2017, 23, 11747–11751

Chiroptical Inversion for Isolated Vibronic Transitions of Supersonic Beam-Cooled Molecules
​J. Lepelmeier, J. L. Alonso-Gómez, F. Mortaheb, U. Boesl, U. Heiz, A. Kartouzian
 Physical Chemistry Chemical Physics, 2017, 19, 21297–21303

Covalent Organic Helical Cages as Sandwich Compound Containers
S. Míguez-Lago, M. M. Cid, J. L. Alonso-Gómez
European Journal of Organic Chemistry, 2016, 34, 5716–5721

The Catalytic Role of Extra Molecules in the Aminolysis or Heterolytic Cleavage of an Iridium Alkoxycarbene Complex
M. Talavera, S. Bolaño, J. Bravo, S. García-Fontán, J. M. J. M. Hermida-Ramón
​Eur. J. Inorg. Chem. 2015, 2015, 4024–4031

A Covalent Organic Helical Cage with Remarkable Chiroptical Amplification
S. Míguez-Lago, A. L. Llamas-Saiz, M. M. Cid, J. L. Alonso-Gómez
Chemistry - A European Journal,  2015, 21, 18085 –18088

Opening access to new chiral macrocycles: from allenes to spiranes
S. Castro-Fernández, M. M. Cid, C. S. López, J. L. Alonso-Gómez
Journal of Physical Chemistry A, 2015, 119, 1747–1753

Absolute Configuration and Conformational Analysis of Chiral Compounds via
Experimental and Theoretical Prediction of Chiroptical Properties: ORD, ECD, and VCD
A. G. Petrovic, N. Berova, J. L. Alonso-Gómez
in Struct. Elucidation Org. Chem. Search Right Tools, 2015, pp. 65–104

Electronic effects of substituents on the stability of the iridanaphthalene compound [Ir[upper bond 1 start]Cp*{=C(OMe)CH=C(o-C6[upper bond 1 end]H4)(Ph)}(PMe3)]PF6.
M. Talavera, J. Bravo, J. Castro, S. García-Fontán, J. M. Hermida-Ramón, S. Bolaño
Dalt. Trans. 2014, 43, 17366–17374

[PF6]2 As catalyst for the meyer-schuster rearrangement of arylpropargylic alcohols under mild conditions
M. Talavera, J. Bravo, L. Gonsalvi, M. Peruzzini, C. Zuccaccia, S. Bolaño
Eur. J. Inorg. Chem. 2014, 2014, 6268–6274

Morpholgical Self-assembly of Enantionpure Allenes for Upstanding Chiral Architectures at Interfaces
Y-Q. Zhang, M. A. Öner, I. R. Lahoz, B. Cirera, C-A. Palma, S. Castro-Fernández, S. Míguez-Lago, M. M. Cid, J. V. Barth, J. L. Alonso-Gómez, F. Klappenberger
Chemical Communications, 2014, 50, 15022–15025

Conformational stable alleno-acetylenic cyclophanes bearing chiral axes
I. R. Lahoz, S. Castro-Fernández, A. Navarro-Vázquez, J. L. Alonso-Gómez, M. M. Cid
Chirality, 2014, 26, 563–573

Preparation and characterization of a halogen-bonded shape-persistent chiral alleno-acetylenic inclusion complex
S. Castro-Fernandez, ́ I. R. Lahoz, A. L. Llamas-Saiz, J. L. Alonso-Gómez, M. M. Cid, A. Navarro-Vazquez
Organic Letters 2014, 16, 1136–1139

Cyanobuta-1,3-dienes as novel electron acceptors for photoactive multicomponent systems
F. Tancini, F. Monti, K. Howes, A. Belbakra, A. Listorti, W. B. Schweizer, P. Reutenauer, J. L. Alonso-Gómez, C. Chiorboli, L. M. Urner, J. P. Gisselbrecht, C. Boudon, N. Armaroli, F. Diederich
Chemistry - A European Journal 2014, 20, 202–216

Acetylenic homocoupling methodology towards the synthesis of 1,3-butadiynyl macrocycles: [142]-Alleno-acetylenic cyclophanes
I. R. Lahoz, A. Navarro-Vázquez, J. L. Alonso-Gómez, M. M. Cid
European Journal of Organic Chemistry 2014, 9, 1915–1924

Cyclometalated Iridium Complexes from Intramolecular C–H Activation of [IrCp*Cl{═C(OMe)CH═C(CH3)R}L] (R = CH3, Ph; L = PPh2Me, PMe3)​
​M. Talavera, S. Bolaño*, J. Bravo, J. Castro, S. Garcı́a-Fontán
Organometallics, 2013, 32, 7241–7244

Formation of Indanone from an Iridanaphthalene Complex​
M. Talavera†, S. Bolaño, J. Bravo, J. Castro, S. Garcı́a-Fontán, J. M. Hermida-Ramón
Organometallics, 2013, 32, 4058–4060

Rotation-Locked 2,6-Pyrido-allenophanes: Characterization of all Stereoisomers
I. R. Lahoz, A. Navarro-Vázquez, A. L. Llamas-Saiz, J. L. Alonso-Gómez, M. M. Cid
Chemistry - A European Journal 2012, 18, 13836–13843

From individual to collective chirality in metal nanoparticles
A. Guerrero-Martínez, J. L. Alonso-Gómez, B. Auguié, M. M. Cid, L. M. Liz-Marzán
Nano Today 2011, 6, 381-400

Fingers Crossed: Optical Activity of a Chiral Dimer of Plasmonic Nanorods
B. Auguié, J. L. Alonso-Gómez, A. Guerrero-Martínez, L. M. Liz-Marzán 
The Journal of Physical Chemistry Letters 2011, 2 (8), 846-851

Intense Optical Activity from Three-Dimensional Chiral Ordering of Plasmonic Nanoantennas
A. Guerrero-Martínez, B. Auguié, J. L. Alonso-Gómez, Z. Dzolic, S. Gómez-Graña,
M. Zinic, M. M. Cid, L. M. Liz-Marzán
Angewandte Chemie International Edition, 2011, 50 (24), 3266-3273

Optically active trialkynyl(phenyl)methane: synthesis and determination of its absolute configuration by vibrational circular dichroism (VCD) and optical rotatory dispersion (ORD)
B. Buschhaus, V. Convertino, P. Rivera-Fuentes, J. L. Alonso-Gómez, A. G. Petrovic, F. Diederich
European Journal of Organic Chemistry 2010, 2452-2456

Thiazolopyrimidine inhibitors of 2-methylerythritol 2,4-cyclodiphosphate synthase (IspF) from Mycobacterium tuberculosis and Plasmodium falciparum
J. G. Geist, S. Lauw, V. Illarionova, B. Illarionov, M. Fischer, T. Gräwert, F. Rohdich, W. Eisenreich, J. Kaiser, M. Groll, C. Scheurer, S. Wittlin, J. L. Alonso-Gómez, W. B. Schweizer, A. Bacher, F. Diederich
ChemMedChem 2010, 5, 1092-1101

Regioselectivity in tether-directed remote functionalization - The addition of a cyclotriveratrylene-based trimalonate to C60 revisited
A. Kraszewska, P. Rivera-Fuentes, G. Rapenne, J. Crassous, A. G. Petrovic, J. L. Alonso-Gómez, E. Huerta, F. Diederich, C. Thilgen
European Journal of Organic 2010, 4402-4411

Mechanistic elucidation of ketenimine-butynoate cycloaddition reaction: role of biradical intermediates in isotopomeric purity of benzyl (1,1a,6,6a-13C4)-6-methyl anthranilic ester 
A. Navarro-Vázquez, J. L. Alonso-Gómez, J. Lugtenburg, M. M. Cid
Tetrahedron 2010, 66, 3855-3860

From relative to absolute configuration of complex natural products: Interplay between NMR, ECD, VCD, and ORD assisted by ab initio calculations 
A. G. Petrovic, A. Navarro-Vázquez, J. L. Alonso-Gómez
Current Organic Chemistry 2010, 14, 1612-1628

Amplification of chirality in monodisperse, enantiopure alleno-acetylenic oligomers
P. Rivera-Fuentes, J. L. Alonso-Gómez, A. G. Petrovic, F. Santoro, N. Harada, N. Berova, F. Diederich
Angewandte Chemie - International Edition 2010, 49, 2247-2250

Enantiomerically pure alleno-acetylenic macrocycles: Synthesis, solid-state structures, chiroptical properties, and electron localization function analysis
P. Rivera-Fuentes, J. L. Alonso-Gómez, A. G. Petrovic, P. Seiler, F. Santoro, N. Harada, N. Berova, H. S. Rzepa,F. Diederich
Chemistry - A European Journal 2010, 16, 9796-9807

Chiral (2,5)Pyrido[74]allenoacetylenic cyclophanes: Synthesis and characterization
J. L. Alonso-Gómez, A. Navarro-Vázquez, M. M. Cid
Chemistry - A European Journal 2009, 15, 6495-6503
​
Chiral induction from allenes into twisted l,l,4,4-tetracyanobuta-1,3- dienes (TCBDs): Conformational assignment by circular dichroism spectroscopy
J. L. Alonso-Gómez, A. G. Petrovic, N. Harada, P. Rivera-Fuentes, N. Berova, F. Diederich
Chemistry - A European Journal 2009, 15, 8396-8400

An enantiomerically pure alleno-acetylenic macrocycle: Synthesis and rationalization of its outstanding chiroptical response
J. L. Alonso-Gómez, P. Rivera-Fuentes, N. Harada, N. Berova, F. Diederich
Angewande Chemie - International Edition 2009, 48, 5545-5548

Synthesis of 2,4-dibromopyridine and 4,4'-dibromo-2,2'-bipyridine. Efficient usage in selective bromine-substitution under palladium-catalysis
R. García-Lago, J. L. Alonso-Gómez, C. Sicre, M. M. Cid
Heterocycles 2008, 75, 57-64

1,3-diethynylallenes (DEAs): Enantioselective synthesis, absolute configuration, and chiral induction in 1,1,4,4-tetracyanobuta-1,3-dienes (TCBDs)
J. L. Alonso-Gómez, P. Schanen, P. Rivera-Fuentes, P. Seiler, F. Diederich
Chemistry - A European Journal 2008, 14, 10564-10568

Regioselectivity in alkenyl(aryl)-heteroaryl Suzuki cross-coupling reactions of 2,4-dibromopyridine. A synthetic and mechanistic study
C. Sicre, J. L. Alonso-Gómez, M. M. Cid
Tetrahedron 2006, 62, 11063-11072

Preparation of 13C4-6-methyl anthranilic ester via a Diels-Alder-type process. An experimental and theoretical study to characterize an unexpected isotope exchange
J. L. Alonso-Gómez, Y. Pazos, A. Navarro-Vázquez, J. Lugtenburg, M. M. Cid
Organic Letters 2005, 7, 3773-3776

Shape-persistent chiral alleno-acetylenic macrocycles and cyclophanes by acetylenic scaffolding with 1,3-diethynylallenes
S. Odermatt, J. L. Alonso-Gómez, P. Seiler, M. M. Cid, F. Diederich
Angewandte Chemie - International Edition 2005, 44, 5074-5078

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  • Chemistry with a Twist
  • People
  • Research
    • Chiroptical Systems >
      • Helical Molecular Orbitals
      • Chiroptical Systems due to Chiral Axes
      • Chiroptical Symmetry Analysis
      • Chiroptical Surfaces & More
    • Metallaaromatic Systems >
      • Metallacycles & More
      • Metallaaromatic Systems
      • Metallaaromatic Biaryl Atropisomers
      • Metallaaromatic Spirobifluorenes
    • Simulations
    • Lab on a Chip
  • Publications
    • Articles
    • Conferences
    • Outreach
  • Funding
  • Contact
    • Links